Styrene can be used for the synthesis of resins, ion exchange resins, and synthetic rubber. This dataset includes the main raw materials, auxiliary materials, energy, atmospheric emissions, and water emissions in the production process. Infrastructure such as production equipment and factory building construction is not included within the boundaries of the dataset. The data inventory is derived from literature data. The production process of styrene includes raw material preparation, preheating, dehydrogenation reaction, oxidation reaction, cooling and condensation, separation and purification, and the process of styrene production.