The downstream products of industrial silicon are mainly polycrystalline silicon, organosilicon, and aluminum alloys, with end applications primarily in electronic devices, daily chemicals, photovoltaics, and semiconductors. This dataset includes material inputs, solid waste, waste, air emissions, and water emissions. Total emissions encompass direct process emissions as well as emissions from the embodied energy of raw materials and electricity. Infrastructure such as production equipment manufacturing and plant construction is excluded from the system boundary of the dataset. The life cycle inventory data were derived from literature sources and partially corrected and supplemented by reference to industry statistics, standards, and emission factor handbooks. The production of metallurgical-grade industrial silicon employs carbothermal reduction. The original method involves processes including batching, feeding, electric arc furnace, casting, demolding, and crushing.