Cradle to Consumer
Identity ID
120d8a4b-67eb-458e-a077-e8fe2629e2ea
Materials
Associated ID
c17d7cef-2d28-4e9b-83f3-2ae88f562c77
Included activities starts
Included activities ends
Description
This dataset is a market dataset, representing the consumption market of the region; the dataset includes the transport of the product from the gate to the consumer end, and the transport service is calculated according to the transport situation of this product in this region. Thiophosphoryl chloride is mainly used as a raw material for producing highly efficient, low-toxicity organophosphorus pesticides, and is also used in the production of organic synthesis phosphorus compounds; Thiophosphoryl chloride is modelled as a pure substance; when modelling this substance the user needs to add a solvent of their choice in the model; the dataset contains the main raw and auxiliary materials, energy, atmospheric emissions, wastewater and solid waste of the production process, in which the preliminary treatment of wastewater in the auxiliary units and the waste gas treatment process are included within the dataset boundary, and infrastructure such as the manufacture of production equipment and the construction of plant buildings is not included within the dataset boundary; the data inventory is formed by merging data from multiple sources; the production activities of this product include phosphorus trichloride synthesis, sulfurisation and condensation.
Activity Description
The production activities of this product include phosphorus trichloride synthesis, vulcanization, condensation and other processes.
Process Description
The chemical formula of thiophosphoryl chloride is PSCl3, and its CAS number is 3982-91-0. It is a colorless, transparent, fuming liquid with a relative density of 1.668, a melting point of -35°C, and a boiling point of 125°C. It is soluble in benzene, carbon disulfide, and carbon tetrachloride. It hydrolyzes slowly in cold water, and reacts and decomposes rapidly in hot water to form hydrogen chloride, hydrogen sulfide, and phosphoric acid. It is volatile, fumes in air, has a pungent odor and strong lachrymatory effect, and is highly hazardous to the eyes and other mucous membranes. It is mainly used as a raw material for the production of high-efficiency, low-toxicity organophosphorus pesticides, and also for the production of organic synthetic phosphorus compounds.
Time period
2019
2026
Geography
China,Sichuan
Macroeconomic value
Business-as-Usual
Data validation
Yes
Technology
Current Technology
Technology comment
The phosphorus trichloride sulfidation method is the core mainstream technology for producing high-purity thiophosphoryl chloride, accounting for 90% of the domestic high-purity thiophosphoryl chloride market. This dataset represents the mainstream technology: mother liquor is added to the phosphorus trichloride reactor, followed by metered molten yellow phosphorus, and chlorine gas is introduced to react and generate phosphorus trichloride. The gas generated from the reaction is washed and condensed; non-condensable gases go to the alkali absorption tower, while a portion of the condensate is refluxed and the remainder is transferred to a buffer tank after inspection. Then, molten sulfur and aluminum strips are added to the reaction kettle; after heating, the phosphorus trichloride intermediate is added dropwise, the mixture is condensed following the reaction, and non-condensable gases are sent to the alkali absorption tower, yielding the thiophosphoryl chloride product. The core chemical equation for this process is: PCl3 + S → PSCl3.