Liquefied petroleum gas (LPG) is a co-product generated during the coal-to-methanol-based ethylene glycol production process and can be used for cooking, heating, and as automotive fuel. The dataset includes primary raw materials, auxiliary materials, energy inputs, and waste outputs from the production process. Environmental burdens associated with production equipment, factory infrastructure construction, and equipment maintenance are excluded from the system boundary of the dataset. The life cycle inventory is compiled from data derived from multiple sources. The process chain for producing LPG from coal-based methanol includes coal powder gasification, purification, methanol synthesis, distillation, olefin separation, olefin cracking to ethylene, ethylene oxidation to ethylene oxide, and ethylene oxide hydration to ethylene glycol.