Ferrophosphorus used in the metallurgical industry is mostly smelted in submerged arc furnaces. Due to the volatility of phosphorus, closed submerged arc furnaces are employed. The raw materials include phosphate rock, iron filings, coke, silica, etc. In current production, ferrophosphorus, a by-product of yellow phosphorus production, is often added to the charge to improve smelting performance and produce high-quality ferrophosphorus. In a closed submerged arc furnace, phosphate rock (mainly Ca3(PO4)2) is mixed with fluxes such as coke and silica, and reacts at high temperature to produce phosphorus gas, calcium silicate, and CO gas.