Sodium hydroxide is an important chemical raw material widely used in industry, medicine, and daily life. This dataset models sodium hydroxide as a pure substance and includes main raw and auxiliary materials, energy use, atmospheric emissions, and waste from the production process. Infrastructure such as manufacturing of production equipment and construction of facilities is not included within the system boundary of the dataset. The life cycle inventory is compiled from multiple data sources. Chlorine and hydrogen are co-products of this process. Allocation follows the method specified in the relevant PCR (Eurochlor, 2022): physical allocation based on stoichiometry is applied to raw salt, and chlorine emissions are allocated solely to the chlorine process. Electricity and steam All other inputs and outputs are allocated by mass to all co-products; the ion-exchange membrane process for caustic soda production includes salt dissolution, primary purification, secondary purification, electrolysis, and dilute brine dechlorination steps.