P-type monocrystalline silicon wafers can be used in the production of photovoltaic cells, with an area of approximately 0.044 m² and a weight of about 15.7 g. The dataset includes major raw and auxiliary materials, energy consumption, atmospheric emissions, and waste generated during the production process. Infrastructure such as manufacturing equipment for production facilities and factory construction is not included within the system boundary of the dataset. The life cycle inventory was compiled from multiple data sources, with certain data corrected and supplemented by reference to industry statistical data, standards, and emission factor handbooks. It is assumed that the target resistivity of the P-type monocrystalline silicon wafer is 1. 6 Ω·cm, boron dopant estimated according to standard GB/T 13389-2014; monocrystalline silicon wafer production uses high-purity polycrystalline silicon as raw material. Firstly, monocrystalline silicon ingots are prepared using the Czochralski (CZ) method (including charging, crystal pulling in a single crystal furnace, and furnace dismantling and cooling). Secondly, the monocrystalline ingots undergo squaring processes (including cropping, squaring, surface grinding, and inspection). Finally, square silicon ingots are sliced using diamond wire (including glue coating, slicing, cleaning, and inspection processes).