This dataset represents a product that is metallic antimony, a silvery-white, slightly blue-lustred brittle semi-metal with the physical characteristics of high hardness, poor ductility and mediocre electrical and thermal conductivity; at room temperature it has good chemical stability and excellent acid- and alkali-corrosion resistance, and is an important basic material and strategic mineral required for the national economy, the national defence industry and scientific and technological development. Its upstream and downstream industries are closely linked: the upstream core raw material is antimony concentrate, with auxiliary raw materials including reducing agents, fluxes and refractory materials; the downstream application scenarios are diverse and critical, with the core application in the flame-retardant field (antimony trioxide as a synergist used in plastics, rubber and textiles), followed by lead–antimony alloy production (suited to lead-acid battery plates, bearings, solders, casting and other scenarios), while also being indispensable in chemical catalysis (polyester PET catalysis) and electronic semiconductors (as a dopant and in arsenide/antimonide compound semiconductors); in addition, high-purity metallic antimony and antimony-based materials play an increasingly important key role in emerging low-carbon technologies such as liquid-metal energy-storage batteries, sodium/lithium-ion battery alloy anodes, thermoelectric materials and antimony-series thin-film photovoltaics. The entire production process focuses on the antimony-ore smelting stage, with the full process covering the entire transformation process from antimony concentrate to the metallic-antimony product. The dataset includes the main raw and auxiliary materials, energy and wastes in the production process; infrastructure such as the manufacture of production equipment and plant construction is not included within the boundary of the dataset; the data inventory is formed by merging data from multiple sources.