This dataset represents a product that is crude zinc, a metallic intermediate product obtained by smelting lead–zinc sinter block, whose core component is zinc, with a zinc content of up to 98%, accompanied by small amounts of impurities such as lead, iron and copper. The product appears as metallic blocks or ingots, has a metallic lustre and a regular physical form that facilitates subsequent processing. Its upstream and downstream industrial chain is closely linked: the upstream core raw material is lead–zinc sinter block; the downstream is mainly applied to the zinc-refining stage, where high-purity zinc can be prepared through electrolytic refining or pyrometallurgical refining processes, and then used to produce zinc-based alloys, galvanized materials, zinc batteries, chemical zinc compounds and other products, broadly supporting the development of metallurgy, automotive, electronics, new energy, chemical and other industrial fields. The entire production process focuses on the smelting stage, with the full process covering the entire transformation process from the input of lead–zinc sinter block to the output of the crude-zinc product. The dataset includes the main raw and auxiliary materials, energy and wastes in the production process; infrastructure such as the manufacture of production equipment and plant construction is not included within the boundary of the dataset; the data inventory is formed by merging data from multiple sources.