Electrochemical oxidation is an efficient wastewater treatment technology that relies on passing an electric current through specific electrode materials to generate highly oxidizing species such as hydroxyl radicals (·OH), which degrade refractory organic compounds in water. This technology offers advantages including simple operation, mild reaction conditions, and absence of secondary pollution, making it suitable for treating industrial wastewater containing persistent organic pollutants (POPs). The electrochemical oxidation process mainly involves two mechanisms: direct oxidation and indirect oxidation. Direct oxidation refers to the oxidation of pollutants through direct electron loss on the anode surface, capable of transforming toxic substances into non-toxic or less toxic compounds, and even completely mineralizing them into CO2 and H2O. Indirect oxidation involves the generation of oxidants, such as active chlorine and hydrogen peroxide, via anode reactions, which subsequently react with organic compounds in wastewater to achieve oxidative degradation. The typical process flow of electrochemical oxidation technology includes three stages: pretreatment, electrolysis, and post-treatment. The pretreatment stage primarily removes suspended solids and sediments from wastewater to reduce electrode damage. The electrolysis stage is the core of the technology, where oxygen and hydrogen are generated through anodic and cathodic electrolysis, along with the formation of peroxides and other reactive oxygen species, which oxidize organic matter in wastewater. The post-treatment stage may include methods such as biological treatment to further purify the water quality.