Sodium sulfite is a white crystalline powder or granule, widely used in the chemical industry, the food industry and the papermaking industry. The dataset includes the main raw and auxiliary materials, energy, atmospheric emissions and wastes of the production process, while infrastructure such as the manufacture of production equipment and plant construction is not included within the dataset boundary; in this dataset, sodium bicarbonate is modelled as a pure substance; when modelling this substance in solution, the user is required to add a solvent of their choice in the model; the data inventory is formed by merging data from multiple sources; the production activities of this product mainly include sulfur dioxide preparation, reaction with sodium carbonate, tail-gas treatment, neutralization, evaporation and crystallization, drying and other processes.