Free fatty acids are one of the substances produced by the decomposition of neutral fat; this dataset includes major raw and auxiliary materials, energy, atmospheric emissions, and waste from the production process, but infrastructure such as production equipment and factory construction is not included within the system boundary of the dataset; the life cycle inventory data were sourced from literature and optimized based on the best available information from 2022; the process flow for producing biodiesel from waste edible oil collection, treatment, and processing includes filtration and pretreatment, esterification, neutralization, separation, decolorization and purification, water and acid removal, distillation, and refining; among these steps, impurities and water in the oil are separated by heating followed by sedimentation. Acid is a co-product of this process.