This dataset represents a product that is new zinc sulfate solution, the core intermediate product produced in the purification process of the hydrometallurgical zinc smelting flow, with clear core characteristics: a zinc content of approximately 140 g/L; impurities such as lead, iron, copper and cadmium in the solution have been largely removed, giving relatively high purity and strong chemical stability, which precisely meets the stringent raw-material purity requirements of the subsequent zinc-electrowinning process. Its upstream and downstream industrial chain is closely linked: the upstream core raw material is the leaching solution produced in the leaching process of hydrometallurgical zinc smelting, and the downstream is directly applied to the electrowinning stage of hydrometallurgical zinc smelting as the core electrolyte of the electrolytic cell, depositing cathode zinc at the cathode through electrochemical action, then preparing finished metallic zinc by casting and finally processing it into galvanized materials, zinc alloys and other end products, broadly supporting the development of industrial fields such as construction, transportation, electric power and manufacturing; it is the key intermediate carrier linking the leaching solution and the electrowinning process in the hydrometallurgical zinc smelting industrial chain. The entire production process focuses on the purification stage of hydrometallurgical zinc smelting, with the full process covering the entire purification-and-transformation process from the input of leaching solution to the output of the new zinc sulfate solution. The dataset includes the main raw and auxiliary materials, energy and wastes in the production process; infrastructure such as the manufacture of production equipment and plant construction is not included within the boundary of the dataset; the data inventory is formed by merging data from multiple sources.