Silicon-barium alloy is mainly produced by the submerged arc furnace method. This method uses barite, silica, coke and steel scraps as the main raw and auxiliary materials. In the submerged arc furnace, the reduction of silicon is mainly carried out according to the reaction mechanism of smelting 75% ferrosilicon, that is, after the SiO2 in the silica is reduced to SiC and SiO, the two intermediate products react with each other or react with SiO2 and C in the charge ingredients to generate silicon, and then the silicon dissolves into iron to form ferrosilicon. The reaction process of barium in the submerged arc furnace is relatively complicated. Since the properties of BaO are similar to CaO, it can be considered that the smelting process of silicon-barium alloy is similar to that of calcium-silicon alloy. The smelting process is continuously carried out in a closed or semi-closed submerged arc furnace. The high temperature in the furnace is maintained through electrode arc heat and resistance heat to achieve efficient reduction and alloying. After the reaction is completed, the silicon-barium alloy melt is separated from the slag, and after being discharged, cast, cooled, crushed and finished, the finished silicon-barium alloy is obtained. The main process flows include: (1) raw material pretreatment and batching; (2) submerged arc furnace charging and smelting; (3) tapping and casting; (4) alloy cooling and crushing; (5) product finishing and packaging.