The electrolytic lead refining production process is fluorosilicate dielectric electrolysis, including the manufacturing of starter plates, lead electrolysis, refining, anode mud washing and filtration and other processes. First, a small amount of cathode lead precipitated in the lead electrolysis process is heated and melted in the starter pot to make lead sheets. Then, together with the conductive copper rods, they are sent to the starter manufacturing unit to make cathodes, and they are laid out according to the center distance requirements of the same pole.
Secondly, after the prepared cathode and anode plates are installed into the electrolytic tank, the lead fluorosilicate solution flowing down from the high-level electrolyte tank is injected into the electrolytic tank for cyclic electrolysis. The electrolysis temperature is 10-50°C and the electrolysis cycle is 7 days. After the cathode lead precipitated during the electrolysis process is washed in the washing tank, except for a small part that is sent to the initial electrode plate pot to produce cathode plates, the remaining part is sent to the electric lead pot for refining and impurity removal; the lead electrolyte is pumped from the circulation tank to the high-level tank for recycling, and an appropriate amount of fluorosilicic acid and additives are regularly added to the circulation tank.
Then, the lead precipitated from the cathode is sent to the lead pot for oxidation and refining to further remove arsenic, antimony, tin and other impurities. The qualified lead liquid after impurity removal is sent to the electric lead ingot casting unit through the lead pump to cast ingots to obtain electric lead products; the refined slag produced by the electric lead pot is sent to the reverberatory furnace for processing.
Finally, the residual electrodes taken out of the lead electrolytic cell are washed by the residual electrode washing machine and returned to the preliminary refining process of the fire method; the washed anode mud and the anode mud sucked by the electrolytic tank vacuum are sent to the mechanical stirring tank for heating and washing to recover the water-soluble lead and fluorosilicic acid entrained in the anode mud. The washed anode mud is filtered using a chamber filter, the filtrate and wash water are returned to the system, and the anode mud after press filtering is sent to the precious lead workshop for further recycling.