Methyl tertiary butyl ether (MTBE) can be used as a gasoline additive; this dataset includes major raw materials, auxiliary materials, energy, atmospheric emissions, water discharges, and waste from the production process, but infrastructure such as production equipment and factory construction is not included within the system boundary of the dataset; the life cycle inventory data are derived from literature; the production process of MTBE involves batching and mixing, dehydration pretreatment, etherification reaction, distillation, extraction, and purification steps.