Sodium hydroxide (NaOH) is a fundamental industrial chemical with wide-ranging applications across industrial, pharmaceutical, and consumer sectors. This dataset models NaOH as a pure substance and covers the consumption of main raw and auxiliary materials, energy inputs, atmospheric emissions, and waste generated during its production. The system boundary excludes infrastructure, such as the manufacturing of process equipment and the construction of production facilities. The life cycle inventory is compiled from multiple data sources. Chlorine and hydrogen are co-products of this process. Allocation follows the method specified in the relevant PCR (Eurochlor, 2022): physical allocation based on stoichiometry is applied to raw salt, and chlorine emissions are allocated solely to the chlorine process. Electricity and steam All other inputs and outputs are allocated by mass to all co-products. The production via the ion-exchange membrane process comprises the following main stages: salt dissolution, primary purification, secondary purification, electrolysis, and dechlorination of the depleted brine.